Hydrogen Desorption Properties of MgH2 + 10 wt% SiO2 + 5 wt% Ni Prepared by Planetary Ball Milling
نویسندگان
چکیده
MgH2 is a very hopeful material for application as hydrogen storage in the solid form. This due to its reversibility and ability store large amounts of hydrogen, which 7.6 wt%. However, this still has weaknesses, namely high operating temperature slow kinetic reactions. Various attempts have been made overcome weakness, including downsizing adding catalyst. In study, double catalyst was used, natural silica extracted from rice husk ash nickel nano powder, with composition + 10 wt% SiO2 5 Ni. The purpose research study effect using these catalysts thermodynamic properties MgH2. Samples were prepared by High Energy Ball Milling (HEBM), variations milling time 1, 5, 10, 15 hours. X-ray Diffraction (XRD) pattern showed presence an impurity phase samples milled It also reduction grain size increasing time. agglomeration occurred From Scanning Electron Microscope (SEM) results can be seen that sample longer time, homogeneously distribute. Thermal investigation lowest desorption achieved hours, 287 °C 288 °C. shows plays role improving characteristics MgH2, while Ni Copyright © 2021 Authors, Published BCREC Group. open access article under CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).
منابع مشابه
Hydrogen Desorption Properties of Nanocrystalline MgH2-10 wt.% ZrB2 Composite Prepared by Mechanical Alloying
Storage of hydrogen is one of the key challenges in developing hydrogen economy. Magnesium hydride (MgH2) is an attractive candidate for solid-state hydrogen storage for on-board applications. In this study, 10 wt.% ZrB2 was co-milled with magnesium hydride at different milling times to produce nanocrystalline composite powder. The effect of milling time and additive on the hydrogen desorption...
متن کاملhydrogen desorption properties of nanocrystalline mgh2-10 wt.% zrb2 composite prepared by mechanical alloying
storage of hydrogen is one of the key challenges in developing hydrogen economy. magnesium hydride (mgh2) is an attractive candidate for solid-state hydrogen storage for on-board applications. in this study, 10 wt.% zrb2 was co-milled with magnesium hydride at different milling times to produce nanocrystalline composite powder. the effect of milling time and additive on the hydrogen desorption ...
متن کاملEffect of Milling Time on Hydrogen Desorption Properties of Nanocrystalline MgH2
Nanocrystalline magnesium hydride powder was synthesized by mechanical milling of MgH2 in a planetary ball mill for various times. The effect of MgH2 structure, i.e. crystallite size, lattice strain, particle size and specific surface area on the hydrogen desorption properties was investigated. A single peak of hydrogen desorption was observed for as-received powder, exhibiting an average parti...
متن کاملاثر زمان آسیاکاری و افزودن آلیاژ Ce-75Ni 25 بر خواص واجذب هیدروژن کامپوزیت پایه هیدرید منیزیم تولیدی بهروش آلیاژسازی مکانیکی
In this study, the composite material with composition of MgH2-10 wt% (25Ce-75Ni) has been prepared by co-milling of magnesium hydride powder with Ce-Ni alloy produced by vacuum arc remelting method. The effect of milling time and additive on magnesium hydride structure, i.e. crystallite size, lattice strain and particle size, and also hydrogen desorption properties of obtained composite were e...
متن کاملEFFECT OF SiC ADDITION ON HYDROGEN DESORPTION PROPERTIES OF NANOCRYSTALLINE MgH2 SYNTESIZED BY MECHANICAL ALLOYING
In this study, the composite material with composition of MgH2-5 wt% SiC has been prepared by co-milling of MgH2 with SiC powder. The effect of milling time and additive on MgH2 structure, i.e. crystallite size, lattice strain, particle size and specific surface area, and also hydrogen desorption properties of obtained composite was evaluated by thermal analyzer method and compared with pure un...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Bulletin of Chemical Reaction Engineering & Catalysis
سال: 2021
ISSN: ['1978-2993']
DOI: https://doi.org/10.9767/bcrec.16.2.10220.280-285